FCUP-Q2006-2020/2021-2S
Topic outline
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Laboratório de Química Física
Código: Q2006 Sigla: Q2006 Nível: 200
To develop the student’s skills for experimental work. This will be achieved through the accomplishment of physical chemistry experiments involving the determination of thermodynamic and kinetics parameters, analysis and interpretation of results and scientific reports writing.
Gibbs Energy Surface diagram ...P and T coordinates of o pure compound....
general equilibrium between 2 phases
Triple points..data & examples
NOTAS | Avaliação | 2021
NEW
Laboratório de Química Física
FCUP-Q2006-2020/2021-2S
Discussão e validação das nota 12h ...quarta 23/06/2021
https://videoconf-colibri.zoom.us/j/84813004224
link para pdf .....
Instruções De funcionamento da LAB_QF2021
Olá Viva,
Estamos numa fase díficil das nossas vidas.
O ataque ao Covid 2019 levou a alterações radicais nas nossas vida e em particular no funcionamento das Unidades curriculares.
Peço a todos os Estudantes que estejam atentos às mensagens que vou enviar via MOODLE.
Para já esta UC vai funcionar em modo remoto ...via ZOOM
Luís
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Interesting!
Antibody responses to SARS-CoV-2 in patients with COVID-19
NATURE medicine
https://www.nature.com/articles/s41591-020-0897-1. pdf?fbclid= IwAR2aVEFdktgKAOhvFcbfHNMb3o1i t_ 3bUgi332kX812oAdMh8HwMZwBmbWY Free access..... Link...
Notas sobre funcionamento e Avaliação
LABQF2021
Plano e notas sobre avaliação
EMAIL PARA CONTACTO E DÚVIDAS:
labqfdqbfcup@gmail.com
PLANO de AULAS: 2021
Plano das aulas 12 $ 13 ... Presenciais. grupos An, Bn, Cn, Dn ... com n=1, 2, 3 .. ..
eg. A1_1 & A1_2 grupo A1 dividido em dois sub-grupos .. um presencialmente e outro por ZOOM na aula.
na semana seguinte trocam...!
Lista de Trabalhos .....
Modulo 1 _ [50 % , (NG(80%+N_Discussão_individual20%)]
Modulo 2 _ [50 % , (apresentação+N_Discussão)]
Temas individuais(10 Slides ... (9 +1 titulo+identificação) + discussão oral )ZOOM, Apresentação. (10 - 15 min (max) de apresentação..... seguida discussão.(10-15 min(max)).Comunicados &informações
Olá Viva,
Hoje vamos começar a primeira aula ONLINE de LABQF2021
Vamos manter o contacto via ZOOM do colibri é fácil precisam apenas de seguir o link
Nesta primeira reunião irei apresentar o plano para as aulas e avaliação.
Obrigado por participarem
Luis
...........................................................................................................................................
NOVA nota informativa (IMPORTANTE)
A comunicação nesta UC deve de seguir as seguintes regras:
1. Envio de trabalhos/Posteres ...
a1) email: "labqfdqbfcup@gmail.com" ;
b1) O "assunto" do email deve de conter o nome do ficheiro em anexo;
c1) Todas as mensagens de email devem de ser enviadas com cópia para todos os membros do grupo de trabalho;
d1) regras para ficheiros referentes aos trabalhos: (e.g. PL1_A1_03.pdf ...para turma PL1, Grupo A1, Trabalho #3)
2. Email com dúvidas sobre questões relacionadas com o grupo ...
a2) O "assunto" do email deve de conter "Dúvida" ;
b2) No corpo de email incluir o nome da turma, grupo. (e.g. PL1_A1 para a turma PL1 e grupo A1)
c2) Todas as mensagens de email devem de ser enviadas com cópia para todos os membros do grupo de trabalho;
3. Email com dúvidas/questões individuais/pessoais ...
a3) O "assunto" do email deve de conter "Questão_problema" em anexo;
b3) No corpo de email incluir o nome da turma, grupo. (e.g. PL1_A1 para a turma PL1 e grupo A1)
c3) Nome do estudante e número mecanográfico;
Obrigado pela colaboração e ajuda
Luís
Agendamento de sessões Colibri _Aulas_ONline
PL1_Slot
Segunda-feira 17h
Join URL: https://videoconf-colibri.
zoom.us/j/83737460135 PL2_Slot
terça-feira 17h
Join URL: https://videoconf-colibri.
zoom.us/j/82603945392 PL3_Slot
quinta-feira 11h
Join URL: https://videoconf-colibri.
zoom.us/j/87810436059
LIST Of TOPICS/THEMATICS, Structure & Planification
NEW ......
........................................................................................................................................................
Ano letivo 2020/2021
Flash Presentation Structure
1 cover slide + 9 Slides (references in footnote) - English text.
10 to 15 min presentation. (Portuguese)
"Topic...."
Some tips to be followed/answered :– What are you going to talk about?
– Explanation/demonstration about what it is!
– On what does it depend & Why?
– What information can we get from it?
– Why did we need it? or What information can we extract from it?
– Example of application or case study!
– Peculiarity/Curiosity information related to the topic!
Slide template LQF 2020/2021 ...
link ..............................
Lista de temas LQF 2020/2021 ...
PL1 - List of topics
#01 |
The Effect of Catalyst on Reaction Rate
Maria de Fátima Jesus Pinto
#02 |
EOS – Equations of State
Joana Filipa Ferreira Peixoto
#03 |
1st Law of Thermodynamics
Joaquim Manuel Igreja Mendes
#04 |
Phase Transition Equilibrium
Cátia Sofia Barros Silva
#05 |
Molecular Interpretation of Heat Capacity
Ana Sofia da Silva Soares
#06 |
Glass Transition Phenomenon
Maria Inês Jesus Amador
#07 |
Acid-base Equilibrium in Organic Solvents
Bianca Marisa Moreira Alves
#08 |
Solid-liquid Equilibrium of Binary Mixtures
Inês Batista Ornelas de Moura Pina
#09 |
Molecular Energetics
Mariana Sofia Martins Teixeira
#10 |
Triple Point in Pure Compounds
Beatriz Maria Pinto Senra
#11 |
Inter and Intramolecular Interactions
Daniela Filipa Teixeira Alves
#12 |
Mechanisms of Chemical Reactions
Letícia Macedo Bravo Soares
#13 |
2nd Law of Thermodynamics
Inês Ribeiro da Conceição
#14 |
Clausius-Clapeyron Equation
Javier Santiago Cortés Salamanca
#15 |
Conductivity Measurements in Electrolyte Solutions
José Jorge Santos Lopes
#16 |
Extended Debye-Hückel Equation
Miguel Amaro Ferreira
PL2 - List of topics
#17 |
Arrhenius Equation
Pedro Miguel Carones Cardoso
#18 |
Deep Eutectic Solvents
Ivan José Santos Almeida
#19 |
3rd Law of Thermodynamics
Jorge Ventura Manuel
#20 |
Phase Diagram of Pure Compounds
Mariana da Silva Bastos
#21 |
Gibbs Phase Rule
André Filipe Moreira Almeida
#22 |
Rate Law of Chemical Reactions
Igor Emanuel Zenha de Oliveira
#23 |
Combustion Bomb Calorimetry
Daniel Augusto Teixeira Afonso
#24 |
Law of Corresponding States
João Amaral Ribeiro da Silva
#25 |
Transition State Theory
Ana Margarida Moreira Pereira
#26 |
Temperature Dependence of Heat Capacity
Gabrielle Neves da Silva
#27 |
Critical Point and Supercritical Fluids
João Manuel Veríssimo Coelho
#28 |
Potential Energy Surfaces
Maria Inês Magalhães Nogueira
#29 |
Temperature Dependence of Ionic Conductivity
Ana Lúcia Maltez de Oliveira
#30 |
Excess Thermodynamic Properties
Vítor Miguel Ferreira Durães
#31 |
Vapor Pressure Equilibrium
Eduardo Alexandre Guedes Oliveira
PL3 - List of topics
#32 |
The Laws of Thermodynamics
Beatriz Norton dos Reis Alarcão Troni
#33 |
Temperature Dependence of Chemical Equilibrium
António Pedro Ribas Couto Rodrigues
#34 |
Kinetic Theory of Gases
Beatriz Ferreira Rodrigues
#35 |
Temperature Dependence of Physical Processes
Marina Alexandra Ribeiro Moreira
#36 |
Solid-solid Phase Transitions
Beatriz Marques Carneiro dos Santos
#37 |
Gas Phase Heat Capacity
Leandro Emanuel Pinho Silva Soares
#38 |
Undercooled Liquids
Fábio André Cunha Gomes
#39 |
Speciation in Acid Base Equilibrium
Daniela Filipa Araújo Fernandes
#40 |
Thermal Conductivity and its Dependence with Temperature
Paulo Fernandes Moreira da Silva
#41 |
Ionization Equilibrium of a Diprotic Acid
Ana Isabel Luciano Boticas
#42 |
Activity Coefficients
Sofia Brites Rocha Pinto de Sousa
#43 |
Isomerization Effect in the Vaporization of Alcohols
Rodrigo José de Sousa Fernandes Cardoso
#44 |
Schröder-Van Laar Equation
Raul Ekberg Dias
#45 |
Hess’s Law
Luís Gomes
#46 |
Non-ideal Solid Liquid Equilibrium
Ana Alexandra Sousa Oliveira
#47 |
Boltzmann Distribution Law
Mariana Gil Carvalho
USEFUL Links.....
Muito interessante, simples ..merece o vosso tempo e reflexão sobre ciência.
All the original episodes and stories in one video - total 66 minutes.The complete FUN TO IMAGINE with Richard Feynman BBC2 in HIGHER RESOLUTION Recorded at Feynman's home in Altadena, California, in 1983 and first broadcast on BBC2.
0.50 Jiggling Atoms
7.18 Fire 12.08 Rubber Bands
14.53 Magnets
22.29 Electricity
32.05 Mirror and Train puzzles
37.46 Seeing Things
43.43 Big Numbers
55.01 Ways of Thinking
NIST .... https://www.nist.gov/
WEIGHTS AND MEASURES
https://www.nist.gov/pml/weights-and-measures/metric-si/si-unitshttps://www.nist.gov/topics/chemistry
https://www.nist.gov/topics/chemical-thermodynamics-chemical-properties
NIST webbook
http://webbook.nist.gov/chemistry/
Dortmund Data Bank
http://www.ddbst.com/en/EED/PCP/PCPindex.php
LAB_notes
Poster Template ..... NEW !!! 2021
Link to the "*.pptx" file "template file"
each poster has to be sent to the following email address: labqfdqbfcup@gmail.com
in "pdf" format.
file name instructions..
e.g
PL1_A1_01.pdf
e.g.
PL1 : Turma
A1 : Grupo A1
01 : trabalho 1
ISOTENISCOPE METHOD
PHYSCHEMlab_#01
Auxiliar Suporte Materials:Pictures .....Isoteniscope details ... Picture Link ...Temperature monitor(Pt1000) ... Picture Link ...PID Temperature Controller (Bath) ... Picture Link ...Vacuum pump (Membrane double stage) ... Picture Link ...Instrumentations data information ....Pressure Sensor – WIKA - Universal Pressure Transmitters UT-10
https://en.wika.com/upload/OI_UT_1x_en_8705.pdf
VWR digital Thermometer TD110 Pt1000
HUBER Compatible PID temperature Control CC1
https://www.huber-online.com/download/manuals/archive/Compatible_Control_CC1_CC2_CC3_V2.0-08_EN.pdf
BÜCHI Vac V-500 – Vacuum
https://www.americaninstrument.com/pdf/5576A-VAC-PUMP.pdf
RAMSAY YOUNG METHOD
PHYSCHEMlab_#02
Link to experiment PDF file..Poster
Link to students web page:
Study of volatility of alcohols;
https://sites.google.com/site/alcoholsvolatility/home
Paper #02_01 ... FPE_Coutinho
Paper #02_02 ... PCCP_2016
Paper #02_03 ... SAFT_Diagram
Auxiliar Suporte Materials:Pictures .....Ebulliometer details ... Picture Link ...Pressure sensor (Baratron MKS) ... Picture Link ...Agilent 34405A 5(1/2) Digit Multimeter ... Picture Link ...Keysight 34461A 6(1/2) Digit Multimeter ... Picture Link ...Temperature monitor(Pt1000) ... Picture Link ...Vacuum pump (Membrane double stage) ... Picture Link ...Instrumentations data information ....Baratron MKS Pressure TransducersAgilent 34405A 5½ Digit Multimeter
KEYSIGHT Digital Multimeters 34461A 6 ½
BÜCHI Vac V-500 – Vacuum
VWR digital Thermometer TD110 Pt1000
MOLECULAR ENERGETICS - COMBUSTION CALORIMETRY
PHYSCHEMlab_#03
Team A _ next week
PAPER_#03_01 ... Mini Bomb
PAPER_#03_02 ... Labtermo
PAPER_#03_03 ... Ballistic bomb calorimetry
PAPER_#03_04 ... Heats of Combustion of Naphthalene
LINK .... Certificate BA NIST
Nist WEBBOOK .... link: https://webbook.nist.gov/chemistry/
Naphthalene ... molar enthalpy of combustion
Pilcher .... source NIST-5156.15 ± 0.92 kJ/mol Ccb Coleman and Pilcher, 1966
LAB_Demo lecture .....PANOPTO link ......
Alerta ...... (para lapso (erro !!!!... :-) ) nos primeiros 6 minutos da aula...
A fórmula estrutural do ácido benzóico está correta!
A fórmula molecular escrita no quadro (C6H6O2) está errada !!
Corrigir para ácido benzóico : C7H6O2
Corrigir o acerto da equação em conformidade.
C7H6O2 (cr) + 15/2 O2 (g) ---> 7CO2 (g) + 3H2O (l)INSTRUMENTATION:
Ballistic Combustion Bomb Gallenkamp
KEYSIGHT Digital Multimeters 34461A 6 ½THERMOCOUPLE type K
The Type K thermocouple (chromel -alumel)
Type K Accuracy (whichever is greater):
Standard: +/- 2.2C or +/- .75%; Special Limits of Error: +/- 1.1C or 0.4%
Calibration Experiment ....Screen Shot
Naphthalene Experiment ....Screen Shot
The quantity of energy evolved by combustion of SRM 39j, benzoic acid, when burned under the standard bomb conditions is given below, where g is the gram mass (mass in vacuum). The reduction of weight in air to mass in vacuum was made using the value 1.320 g·cm-3 for the density of benzoic acid at 25 °C.
Certified Value: 26 434 ± 3 J/g
C7H6O2 (cr) + 15/2 O2 (g) ---> 7CO2 (g) + 3H2O (l)
E (J/K) = 26 434 x m(AB) / Δ T (AB)
m(AB) – Experimental mass of benzoic acid (gram)
Δ T (AB) – Temperature change of the calibration experiment
Naphthalene
C10H8 (cr) + 12 O2 (g) ---> 10 CO2 (g) + 4 H2O (l)
u (naf) = - <E> (J/K) x Δ T (naf) / m(naf)
m(naf) – Experimental mass of naphthalene (gram)
Δ T (naf) – Temperature change of the sample experiment
Δ Um = u (naf) x MM (naf) ; Δ Hm = Δ Um + Δ n (g).RT
Δ n = n[CO2 (g)] - n[O2 (g)] = 10 - 12 = - 2 mol
.......................
EXPERIMENTAL DATA ...
link to excel File ......
SOLID_LIQUID EQUILIBRIUM
PHYSCHEMlab_#04
Team B _ next week
Paper_#04_01 ...paper JACS
Paper_#04_02 ... paper Phywe
LAB Demo Lecture.....
PANOPTO link ......
Bif & NAF ... screen Shot
Experimental results & details:
Instrumentation:Datalogger: Agilent model 34972A LXI Data Acquisition / Data Logger Switch Unit. .....6 1/2-digit (22-bit) internal DMM.
PC + Agilent Bench Link Software.
Temperature sensor = Thermocouple type T
https://www.thermocoupleinfo.com/type-t-thermocouple.htm
It consist of positive leg made of an Copper wire and negative leg made of Constantan (Cu & Cu-Ni) alloy wire
Type T Accuracy (whichever is greater):
- Standard: +/- 1.0C or +/- .75%
- Special Limits of Error: +/- 0.5C or 0.4%
Additional information :
link to EXCEL data File: Link ......
IONIZATION EQUILIBRIUM OF GLYCYLGLYCINE
PHYSCHEMlab_#05
Electrolyte Conductivity measurements RADIOMETER ... Link
JACS paper ... Link
Paper Chemical education .... Link
NIST_conductivity ..... LinkLink to PANOPTO ..... lecture
Titration ....pH & K
Instrumentation: Experimental setup.
pH ... Titration Curve & Speciation SIMULATOR
Link to Excel File .... NOVA VERSÃO !!
Experimental Results:
link to excel File: ....... Link
RATE OF REDUCTION OF HEXACYANOFERRATE(III) BY ASCORBIC ACID
PHYSCHEMlab_#06
Spectroscopy slides ...link
Experimental notes_link
Kinetics_notes_link
Paper_#06_01 ..JACS 1968 .... Link
Paper_#06_02 ..TALANTA 1996 .... Link
Link to PANOPTO ..... lecture
................................................................................................
Experimental Results:
Link to Excel file .... NOVA VERSÃO ..MAIS COMPLETA !
